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oai:recercat.cat:2445/531942025-12-04T21:43:41Zcom_2072_1057col_2072_478917col_2072_478933

Stereoselective Acetate Aldol Reactions From Metal Enolates Ariza Piquer, Xavier García Gómez, Jordi Romea, Pedro Urpí Tubella, Fèlix Reacció aldòlica Productes naturals Quiralitat Catàlisi Aldol reaction Natural products Chirality Catalysis This review deals with metal enolate-mediated stereoselective acetate aldol reactions. It summarizes recent advances on aldol additions of unsubstituted metal enolates from chiral auxiliaries, stoichiometric and catalytic Lewis acids, or acting in substrate- controlled reactions, which provide stereocontrolled aldol transformations that allow the efficient synthesis of structurally complex natural products. 2014-04-02T11:09:11Z 2014-04-02T11:09:11Z 2011 2014-04-02T11:09:11Z info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion 0039-7881 https://hdl.handle.net/2445/53194 597521 eng Versió postprint del document publicat a: http://dx.doi.org/10.1055/s-0030-1260040 Synthesis. Journal of Synthetic Organic Chemistry, 2011, vol. 2011, num. 14, p. 2175-2191 http://dx.doi.org/10.1055/s-0030-1260040 (c) Georg Thieme Verlag, 2011 info:eu-repo/semantics/openAccess 19 p. application/pdf Georg Thieme Verlag Articles publicats en revistes (Química Inorgànica i Orgànica)