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Reductive Elimination from Cyclometalated Platinum(IV) Complexes To Form Csp2−Csp3 Bonds and Subsequent Competition between Csp2−H and Csp3−H Bond Activation Crespo Vicente, Margarita Ma. Anderson, Craig M. Kfoury, Nicole Font Bardia, Ma. Mercedes Calvet Pallàs, Maria Teresa Lligands Hidrocarburs Ligands Hydrocarbons <p>Reductive elimination reactions of the cyclometalated platinum(IV) compounds [PtMe2Br{C6H4CH NCH2(4-ClC6H4)}L] (L = SMe2, PPh3) to form Csp3−Csp2 bonds, followed by either exclusive Csp2−H bond activation (L = SMe2) or competition between Csp2−H and Csp3−H bond activation (L = PPh3) are reported. Reductive elimination to form a C−Br bond is also reported.</p> 2024-05-07T12:54:17Z 2024-05-07T12:54:17Z 2012 2024-05-07T12:54:22Z info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Versió postprint del document publicat a: https://doi.org/10.1021/om300303a Organometallics, 2012, vol. 31, num.12, p. 4401-4404 https://doi.org/10.1021/om300303a (c) American Chemical Society, 2012 info:eu-repo/semantics/openAccess American Chemical Society Articles publicats en revistes (Química Inorgànica i Orgànica)