2026-04-14T02:55:42Zhttps://recercat.cat/oai/request

oai:recercat.cat:2445/1835862025-12-05T14:29:52Zcom_2072_1057col_2072_478917col_2072_478923

Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures Sánchez-Férez, Francisco Calvet Pallàs, Maria Teresa Font Bardia, Ma. Mercedes Pons, Josefina Radiocristal·lografia Compostos organometàl·lics Estructura cristal·lina (Sòlids) X-ray crystallography Organometallic compounds Layer structure (Solids) Extensively research has been devoted to the isolation and characterization of Cu(II) coordination polymers. Since many aspects can influence the final crystal structure, the effect of the solvent molecules through intermolecular interactions has been proven to be a determining factor. Herein, we elucidated the structure of two Cu(II) concomitant 1D polymers containing piperonylic acid (HPip) and 4,4 -bipyridine (4,4-bipy), which were simultaneously crystallized and subsequently isolated changing the synthetic conditions. Complex {[Cu(Pip)2(4,4-bipy)]}n (1) exhibits zig-zag polymeric chains while {[Cu(Pip)2(4,4 -bipy)(H2O)]¿ 1/2(4,4-bipy)¿(DMF)}n (2) displays linear polymeric chains stacked by water¿¿¿carboxylate intermolecular interactions, forming voids occupied by alternated guest 4,4-bipy and DMF molecules. 2022-02-28T12:36:51Z 2023-07-05T05:10:19Z 2021-07-05 2022-02-28T12:36:52Z info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Versió postprint del document publicat a: https://doi.org/10.1016/j.molstruc.2021.130219 Journal of Molecular Structure, 2021, vol. 1235, num. 130219 https://doi.org/10.1016/j.molstruc.2021.130219 cc-by-nc-nd (c) Elsevier B.V., 2021 https://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Elsevier B.V. Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)