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A Ferromagnetic Salicylaldoximate/Azide MnII2MnIII6 Cluster with an S = 17 Ground State and a Single-Molecule-Magnet Response Vicente Castillo, Ramón El Fallah El Boufrahi, Mohamed Salah Casanovas Bayo, Berta Font Bardia, Ma. Mercedes Escuer Fité, Albert Geoquímica Magnetisme Estructura cristal·lina (Sòlids) Geochemistry Magnetism Layer structure (Solids) One new MnII 2MnIII 6 cluster exhibiting an S = 17 spin ground state and single-molecule-magnet properties has been designed linking MnIII 3-salicylaldoximate triangles and tetracoordinated MnII cations by means of end-on azido bridges. The ferromagnetic coupling has been rationalized as a function of their structural parameters. 2020-05-14T17:30:00Z 2020-05-14T17:30:00Z 2016-06-20 2020-05-14T17:30:00Z info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion 0020-1669 https://hdl.handle.net/2445/160321 662822 eng Versió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.6b00662 Inorganic Chemistry, 2016, vol. 55, num. 12, p. 5735-5737 https://doi.org/10.1021/acs.inorgchem.6b00662 (c) American Chemical Society , 2016 info:eu-repo/semantics/openAccess 10 p. application/pdf American Chemical Society Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)