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oai:recercat.cat:2445/1597232025-12-04T21:42:07Zcom_2072_1057col_2072_478917col_2072_478933

Negatively charged metallacarborane redox couples with both members stable to air Lupu, Marius Zaulet, Adnana Teixidor, Francesc Ruiz Sabín, Eliseo Viñas, Clara Cobalt Reacció d'oxidació-reducció Cobalt Oxidation-reduction reaction It was possible to synthesize and isolate redox couples in which both partners are negatively charged. The handy framework is [3,3'-Co(1,2-closo-C2B9H11)2]-. The E½ potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3'-Co(1,2-closo-C2B9H7I4)2]- is the most favorable as it is isolatable and stable in air. 2020-05-12T10:09:43Z 2020-05-12T10:09:43Z 2015-04-27 2020-05-12T10:09:43Z info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion 0947-6539 https://hdl.handle.net/2445/159723 653202 eng Versió postprint del document publicat a: https://doi.org/10.1002/chem.201406244 Chemistry-A European Journal, 2015, vol. 21, num. 18, p. 6888-6897 https://doi.org/10.1002/chem.201406244 (c) Wiley-VCH, 2015 info:eu-repo/semantics/openAccess 10 p. application/pdf Wiley-VCH Articles publicats en revistes (Química Inorgànica i Orgànica)