2026-04-13T02:11:24Zhttps://recercat.cat/oai/request

oai:recercat.cat:2445/1597232025-12-04T21:42:07Zcom_2072_1057col_2072_478917col_2072_478933

00925njm 22002777a 4500 dc Lupu, Marius author Zaulet, Adnana author Teixidor, Francesc author Ruiz Sabín, Eliseo author Viñas, Clara author 2020-05-12T10:09:43Z 2020-05-12T10:09:43Z 2015-04-27 2020-05-12T10:09:43Z It was possible to synthesize and isolate redox couples in which both partners are negatively charged. The handy framework is [3,3'-Co(1,2-closo-C2B9H11)2]-. The E½ potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3'-Co(1,2-closo-C2B9H7I4)2]- is the most favorable as it is isolatable and stable in air. Cobalt Reacció d'oxidació-reducció Cobalt Oxidation-reduction reaction Negatively charged metallacarborane redox couples with both members stable to air