2026-04-17T02:26:16Zhttps://recercat.cat/oai/request

oai:recercat.cat:2445/1544842025-12-04T20:58:32Zcom_2072_1057col_2072_478796col_2072_478917

00925njm 22002777a 4500 dc Vela Llausí, Sergi author Fumanal Quintana, María author Ribas Ariño, Jordi author Robert, V. author 2020-03-31T09:29:00Z 2020-03-31T09:29:00Z 2016-04-15 2020-03-31T09:29:00Z Complete active space self-consistent field theory (CASSCF) calculations and subsequent second-order perturbation theory treatment (CASPT2) are discussed in the evaluation of the spin-states energy difference (ΔHelec) of a series of seven spin crossover (SCO) compounds. The reference values have been extracted from a combination of experimental measurements and DFT  +  U calculations, as discussed in a recent article (Vela et al., Phys Chem Chem Phys 2015, 17, 16306). It is definitely proven that the critical IPEA parameter used in CASPT2 calculations of ΔHelec, a key parameter in the design of SCO compounds, should be modified with respect to its default value of 0.25 a.u. and increased up to 0.50 a.u. The satisfactory agreement observed previously in the literature might result from an error cancellation originated in the default IPEA, which overestimates the stability of the HS state, and the erroneous atomic orbital basis set contraction of carbon atoms, which stabilizes the LS states. Ferro Lligands Iron Ligands On the zeroth-order Hamiltonian for CASPT2 calculations of spin crossover compounds