2026-04-14T03:52:30Zhttps://recercat.cat/oai/request

oai:recercat.cat:2445/1541862025-11-19T20:56:03Zcom_2072_1057col_2072_478917col_2072_478933

urn:hdl:2445/154186 Controlled heterometallic composition in linear trinuclear [LnCeLn] lanthanide molecular assemblies Velasco Amigó, Verónica Barrios Moreno, Leoní Alejandra Schütze, Mike Roubeau, Olivier Luis Vitalla, Fernando Teat, Simon J. Aguilà Avilés, David Aromí Bedmar, Guillem Terres rares Imants Compostos de coordinació Rare earths Magnets Coordination compounds The combination of two different β-diketone ligands facilitates the size-controlled assembly of pure heterometallic [LnLn′Ln] linear compounds thanks to two different coordination sites present in the molecular scaffold. [HoCeHo], [ErCeEr], and [YbCeYb] analogues are presented here and are characterized both in the solid state and in solution, demonstrating the selectivity of this unique method to produce heterometallic 4f molecular entities 2020-03-27T10:12:49Z 2020-09-10T05:10:23Z 2019-09-10 2020-03-27T10:12:49Z info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Versió postprint del document publicat a: https://doi.org/10.1002/chem.201903829 Chemistry-A European Journal, 2019, vol. 25, num. 67, p. 15228-15232 https://doi.org/10.1002/chem.201903829 (c) Wiley-VCH, 2019 info:eu-repo/semantics/openAccess Wiley-VCH Articles publicats en revistes (Química Inorgànica i Orgànica)