2026-04-13T04:05:27Zhttps://recercat.cat/oai/requestoai:recercat.cat:2445/1541852025-12-04T21:43:44Zcom_2072_1057col_2072_478917col_2072_478933
RECERCAT
author
Diego, Rosa
author
Darawsheh, Mohanad D.
author
Barrios Moreno, Leoní Alejandra
author
Sadurní, Anna
author
Garcia-Anton, Jordi
author
Lloyd-Williams, Paul
author
Teat, Simon J.
author
Roubeau, Olivier
author
Aguilà Avilés, David
author
Aromí Bedmar, Guillem
2020-03-27T09:51:05Z2020-11-23T06:10:24Z2019-11-232020-03-27T09:51:06Z
A new bis-(β-diketone) ligand featuring built-up structural asymmetry yields non-symmetric Fe(iii) and Ga(iii) dinuclear, triple-stranded helicates by design. Their structural properties have been studied, both in solid state and in solution, and compared with their corresponding symmetric analogues. The robustness observed shows the potential of this synthetic strategy to develop non-symmetric helicoidal motifs with specific functional groups. © 2019 The Royal Society of Chemistry.
(c) Diego, Rosa et al., 2019 info:eu-repo/semantics/openAccess
Lligands
Coure
Difracció de raigs X
Ligands
Copper
X-rays diffraction
Designed asymmetric coordination helicates with bis-beta-diketonate ligands
info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion