2026-04-17T06:42:08Zhttps://recercat.cat/oai/request

oai:recercat.cat:2445/1541272025-12-04T21:41:01Zcom_2072_1057col_2072_478917col_2072_478933

Four lanthanide-carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: syntheses, structures, luminescent and magnetic properties Hu, Min Zhao, Hui Sañudo Zotes, Eva Carolina Chen, Min Luminescència Propietats magnètiques Luminescence Magnetic properties Four new lanthanide-carboxylate coordination polymers of the formula [Ln3L4(phen)4(H2O)4](ClO4)·2H2O, (Ln = Dy (1), Tb (2), Ho (3) and Er (4), L = 2,3-naphthalenedicarboxylate and phen = 1,10-phenanthroline) were solvothermally synthesized. Their structures as well as magnetic and photoluminescent properties were completely investigated. Complexes 1-4 are isostructural and exhibit 1D ribbon-like chains with envelope-like sixteen-membered rings. The DyIII and TbIII complexes show the corresponding characteristic luminescence in the visible region and the ErIII complex shows luminescence in the near-infrared region upon excitation with UV rays. Studies on the magnetic properties are reported. The Dy(III) analog complex 1 exhibits slow magnetic relaxation and could be a new example of a Dy(III) SMM (single molecule magnet). 2020-03-27T07:40:28Z 2020-03-27T07:40:28Z 2015-08-29 2020-03-27T07:40:28Z info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2015.08.030 Polyhedron, 2015, vol. 101, p. 270-275 https://doi.org/10.1016/j.poly.2015.08.030 cc-by-nc-nd (c) Elsevier Ltd, 2015 http://creativecommons.org/licenses/by-nc-nd/3.0/es info:eu-repo/semantics/openAccess Elsevier Ltd Articles publicats en revistes (Química Inorgànica i Orgànica)