2026-04-14T06:59:21Zhttps://recercat.cat/oai/request

oai:recercat.cat:2445/1533032025-12-04T20:57:25Zcom_2072_1057col_2072_478796col_2072_478917

00925njm 22002777a 4500 dc Flores Tapia, Nelly Esther author Sirés Sadornil, Ignacio author Rodríguez González, Rosa Ma. author Centellas Masuet, Francesc A. author Cabot Julià, Pere-Lluís author Garrido Ponce, José Antonio author Brillas, Enric author 2020-03-23T09:40:35Z 2020-03-23T09:40:35Z 2016-08-04 2020-03-23T09:40:35Z The degradation of 100 mL of solutions containing 4-hydroxyphenylacetic acid in 0.050 M Na2SO4 at pH 3.0 has been performed by anodic oxidation with electrogenerated H2O2 (AO-H2O2) using a stirred tank reactor equipped with a boron-doped diamond (BDD) anode and an air-diffusion cathode. An almost total mineralization with 95.5% total organic carbon (TOC) removal was achieved for a 1.03 mM substrate solution at 100 mA cm-2. The effect of current density between 16.7 and 100 mA cm-2 and 4-hydroxyphenylacetic acid content between 0.21 and 2.06 mM was examined. Greater current efficiency with lower specific energy consumption and smaller mineralization was found at low current density and high substrate concentration. The TOC abatement as well as the 4-hydroxyphenylacetic acid concentration decay obeyed a pseudo-first-order kinetics. The oxidation role of hydroxyl radical formed from water discharge at the BDD anode is explained on the basis of its electrogeneration rate and competitive wasting reactions. 4-Hydroxybenzenemethanol and its derivative 4-hydroxybenzenealdehyde were identified as primary aromatic by-products by gas chromatography-mass spectrometry. Ion-exclusion HPLC allowed the detection of low amounts of the persistent oxalic acid during the AO-H2O2 process. The remaining TOC in final electrolyzed solutions is related to the presence of a large proportion of unidentified by-products that are even more recalcitrant than common short-linear aliphatic carboxylic acids. Depuració d'aigües residuals Oxidació electroquímica Purification of sewage Electrolytic oxidation Removal of 4-hydroxyphenylacetic acid from aqueous medium by electrochemical oxidation with a BDD anode: mineralization, kinetics and oxidation products