2026-04-05T12:43:48Zhttps://recercat.cat/oai/requestoai:recercat.cat:2445/1431622025-12-04T21:45:16Zcom_2072_1057col_2072_478917col_2072_478933
RECERCAT
author
Mondal, Amit Kumar
author
Jover Modrego, Jesús
author
Ruiz Sabín, Eliseo
author
Konar, Sanjit
2019-10-25T09:49:37Z2019-10-25T09:49:37Z2018-10-232019-10-25T09:49:37Z
The first example of a pentacoordinate CoII single-ion magnet based on a P-donor ligand with vacant octahedral coordination geometry is reported here. Thorough magnetic measurements reveal the presence of field induced slow relaxation behavior with an easy-plane magnetic anisotropy. The combined theoretical and experimental studies disclose that direct and quantum tunneling processes become dominant at low temperature to relax the magnetization; however, from the thermal dependence of relaxation time it can be observed that the optical or acoustic Raman processes become important to the overall relaxation process.
(c) Mondal, Amit Kumar et al., 2018 info:eu-repo/semantics/openAccess
Imants
Anisotropia
Relaxació magnètica
Lligands
Magnets
Anisotropy
Magnetic relaxation
Ligands
Single-ion magnetic anisotropy in a vacant octahedral Co(II) complex
info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion