2026-04-17T07:33:45Zhttps://recercat.cat/oai/requestoai:recercat.cat:2445/1294772025-12-04T21:41:40Zcom_2072_1057col_2072_478917col_2072_478933
RECERCAT
author
Kennington, Stuart C. D.
author
Ferré, Laura
author
Romo Fernández, Juan Manuel
author
Romea, Pedro
author
Urpí Tubella, Fèlix
author
Font Bardia, Ma. Mercedes
2019-03-04T15:22:32Z2019-03-04T15:22:32Z2017-06-152019-03-04T15:22:32Z
Direct nickel-catalyzed alkylation of chiral N-acyl-4-isopropyl-1,3-thiazolidine-2-thiones using a commercially available nickel(II) complex, (Me3P)2NiCl2, has been developed for tropylium and trityl tetrafluoroborate salts. The reaction provides a single diastereomer of the corresponding adducts in good to high yields, which, in turn, can be easily converted into a wide array of enantiomerically pure compounds that are difficult to obtain by other asymmetric procedures.
(c) American Chemical Society , 2017 info:eu-repo/semantics/openAccess
Catàlisi
Níquel
Quiralitat
Catalysis
Nickel
Chirality
Diastereoselective and catalytic α-alkylation of chiral N-acyl thiazolidinethiones with stable carbocationic salts
info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion