2026-04-14T02:51:23Zhttps://recercat.cat/oai/request

oai:recercat.cat:2445/1188282025-12-04T20:59:08Zcom_2072_1057col_2072_478796col_2072_478917

00925njm 22002777a 4500 dc Lamiel Garcia, Josep Oriol author Cuko, Andi author Calatayud, Mònica author Illas i Riera, Francesc author Bromley, Stefan Thomas author 2017-12-20T12:28:29Z 2017-12-20T12:28:29Z 2017-01-21 2017-12-20T12:28:29Z Bottom-up and top-down derived nanoparticle structures refined by accurate ab initio calculations are used to investigate the size dependent emergence of crystallinity in titania from the monomer upwards. Global optimisation and data mining are used to provide a series of ( TiO2) N global minima candidates in the range N = 1-38, where our approach provides many new low energy structures for N > 10. A range of nanocrystal cuts from the anatase crystal structure are also considered up to a size of over 250 atoms. All nanocrystals considered are predicted to be metastable with respect to non-crystalline nanoclusters, which has implications with respect to the limitations of the cluster approach to modelling large titania nanosystems. Extrapolating both data sets using a generalised expansion of a top-down derived energy expression for nanoparticles, we obtain an estimate of the non-crystalline to crystalline crossover size for titania. Our results compare well with the available experimental results and imply that anatase-like crystallinity emerges in titania nanoparticles of approximately 2-3 nm diameter. Diòxid de titani Nanopartícules Nanocristalls semiconductors Nanoestructures Titanium dioxide Nanoparticles Semiconductor nanocrystals Nanostructures Predicting size-dependent emergence of crystallinity in nanomaterials: titania nanoclusters versus nanocrystals