2026-04-17T01:07:26Zhttps://recercat.cat/oai/request

oai:recercat.cat:2445/1083862025-12-04T21:40:23Zcom_2072_1057col_2072_478917col_2072_478933

00925njm 22002777a 4500 dc Flores-Gaspar, Areli author Orgué Gassol, Sílvia author Grabulosa, Arnald author Riera i Escalé, Antoni author Verdaguer i Espaulella, Xavier author 2017-03-14T08:59:50Z 2017-03-14T08:59:50Z 2014-12-22 2017-03-14T08:59:50Z In non-coordinating solvents, borane was shown to be an efficient directing group for the stereoselective 1,2-addition of organolithium reagents to P-stereogenic N-phosphanylimines. Selectivity was reversed in coordinating solvents. This process can lead to novel ligand scaffolds for asymmetric catalysis. Compostos organometàl·lics Lligands (Bioquímica) Catàlisi asimètrica Organometallic compounds Ligands (Biochemistry) Enantioselective catalysis Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines