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Evaluation of the effect of coupling agent on the kinetic and mechanical properties of a 3D printable dual curing epoxy/acrylate system Escribá Flores, Armando Alfredo Fernández Francos, Xavier Ferrando Piera, Francesc Fabregat Sanjuan, Albert Àrees temàtiques de la UPC::Enginyeria dels materials Dual-curing Vat photopolymerization 3D printing Multi-material High mechanical performance In recent years, the use of vat photopolymerization in additive manufacturing technology has created a prominent potential in the world manufacturing industry due to its adaptability and quick production capabilities. However, a challenge faced by this technology is creating large-sized parts and ensuring the geometric versatility of processed parts. The physical and mechanical properties of existing materials limit their processing, affecting their final applications. Moreover, dual-curing systems allow new possibilities to 3D printing if shape geometry is changed after the first curing stage and fixed in the second curing stage. This study aims to address these challenges by developing a dual-curing system involving epoxy/acrylic resins. We assess the kinetic and mechanical behavior, focusing on variations in the network coupling agent. The initial curing stage of a low viscous formulation, achieved through processing on a DLP 3D printer (partially cured), produces a flexible material allowing deformations up to 160 %. The second curing stage, achieved through thermal treatment, transforms the material into a rigid system with an impressive maximum tensile strength close to 80 MPa. We compare the contribution of the bonding agent in partial and total cured states. Comprehensive mechanical tests have been performed, including tension and shear evaluations. Results have been favorably aligned with relevant literature. The dual-curing approach shows promise in expanding 3D printing vat photopolymerization applications, providing new design and manufacturing possibilities by enhancing material availability. Our findings emphasize the benefits of the dual-curing system, including low viscosity, shape manipulation during intermediate curing that allows complex geometries with fast procedures and without the need of supports and exceptional strength and durability achieved in the final curing phase. Results on mechanical characterization in joints show that dual curing resins could be attractive in applications where different parts must be joined and precise alignment and structural integrity are crucial. The main reason for that is the interaction with the bonding agent in each state of the dual curing. This work was funded by the Spanish Ministry of Science and Innovation (MCIN/AEI/10.13039/501100011033) through R&D projects PID2020-115102RB-C21 and PID2020-115102RB-C22, and also by Generalitat de Catalunya (2021-SGR-154). Armando Escribá acknowledges the Martí Franquès Research Fellowship Programme (2021PMFBS- 08). X. Fernández-Francos acknowledges the Serra-Húnter programme (Generalitat de Catalunya). Peer Reviewed Postprint (published version) 2025-04-16 Article https://www.sciencedirect.com/science/article/abs/pii/S0014305725001661 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115102RB-C21/ES/PROCESADO DUAL DE VITRIMEROS: MATERIALES SOSTENIBLES/ info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115102RB-C22/ES/PROCESADO DUAL DE VITRIMEROS: IMPRESION 3D/ http://creativecommons.org/licenses/by-nc-nd/4.0/ Open Access Attribution-NonCommercial-NoDerivatives 4.0 International Elsevier