2026-04-18T01:48:38Zhttps://recercat.cat/oai/request

oai:recercat.cat:2117/1062352026-01-24T04:50:42Zcom_2072_1033col_2072_452950

NH2- or PPh2-functionalized linkers for the immobilization of palladium on magnetite nanoparticles? Caparrós, Francisco J. Guarnizo, A Rossell Abrodos, Marta-Dacil Angurell Purroy, Inmaculada Seco García, Miquel Angel Müller Jevenois, Guillermo Llorca Piqué, Jordi Rossell Alfonso, Josep Oriol Universitat Politècnica de Catalunya. Departament d'Enginyeria Química Universitat Politècnica de Catalunya. NEMEN - Nanoenginyeria de materials aplicats a l'energia Àrees temàtiques de la UPC::Enginyeria química Magnetite Nanoparticles Nanopartícules Nanoparticles Immobilization of palladium on magnetite nanoparticles has been carried out with the assistance of two differently functionalized linkers containing phosphino- or amino-terminated groups. The linkers have been anchored to the magnetite surface by means of catechol, mercapto or carboxylate groups. The nature of the resulting Pd nanoparticles deposited has been examined by HAADF-STEM images and XPS electron spectroscopy. The efficiency of the two kinds of catalysts has been checked and compared for the Suzuki–Miyaura reaction, 4-nitrophenol reduction and styrene hydrogenation. The results evidence that the nanoparticles equipped with the phosphino fragment are better catalysts than those functionalized with the amino group and, in some processes, they are among the most active catalysts reported in the literature. Postprint (published version) 2017-01-01 Article Caparrós, F., Guarnizo, A., Rossell, M., Angurell, I., Seco, M., Müller, G., Llorca, J., Rossell, O. NH2- or PPh2-functionalized linkers for the immobilization of palladium on magnetite nanoparticles?. "RSC advances", 1 Gener 2017, vol. 7, núm. 45, p. 27872-27880. 2046-2069 https://hdl.handle.net/2117/106235 10.1039/c7ra03639f eng http://pubs.rsc.org/en/Content/ArticleLanding/2017/RA/C7RA03639F#!divAbstract http://creativecommons.org/licenses/by-nc/3.0/es/ Open Access Attribution-NonCommercial 3.0 Spain 9 p. application/pdf