2026-04-13T02:06:38Zhttps://recercat.cat/oai/request

oai:recercat.cat:2072/5357692024-12-20T19:46:58Zcom_2072_300912com_2072_4427col_2072_301309

00925njm 22002777a 4500 dc Cong, Fei author Mega, Riccardo S. author Chen, Jinhong author Day, Craig S. author Martin, Ruben author 2022-11-23 Herein, we report a Cu-mediated trifluoromethylation of carbonyl-type compounds and unactivated olefins enabled by visible-light irradiation via σ C(sp3)−C bond-functionalization. The reaction is distinguished by its modularity, mild conditions and wide scope—even in the context of late-stage functionalization—thus offering a complementary approach en route to valuable C(sp3)−CF3 architectures from easily accessible precursors. http://hdl.handle.net/2072/535769 https://doi.org/10.1002/anie.202214633 Trifluoromethylation of Carbonyl and Unactivated Olefin Derivatives by C(sp3)–C Bond Cleavage