2026-04-14T04:15:47Zhttps://recercat.cat/oai/request

oai:recercat.cat:2072/5296302024-12-20T19:34:19Zcom_2072_300912com_2072_4427col_2072_301309

00925njm 22002777a 4500 dc Su, Lijun author Méndez Màlaga, Maria author Jiménez-López, Jesús author Zhu, Miaoli author Xiao, Yaoming author Palomares Gil, Emilio José author 2021-07-12 Previous studies have revealed that for some perovskite compositions, power conversion efficiencies (PCEs) improved after storing the devices in different ambient conditions. With the aim of better understanding such improvements, we focus our attention on the carrier/ionic dynamic kinetics of fresh and aged PSCs with different perovskite compositions (MAPbI3 and MAPbBr3) and using spiro-OMeTAD as HTM. For that, we use transient photovoltage (TPV), a technique used to analyse the different recombination kinetics at equilibrium and at different illumination times. We observe that the aging treatment causes significant changes on the kinetics behaviour for bromide-based devices, resulting in a positive influence on the cell performance (from 3.5 % to 6.1 % PCE, in reverse scan). However, the kinetics for those iodide-based perovskite solar cells remains unchangeable (from 16.3 % to 15.0 % PCE, in reverse scan). http://hdl.handle.net/2072/529630 https://doi.org/10.1002/cplu.202100204 Analysis of the Oxygen Passivation Effects on MAPbI3 and MAPbBr3 in Fresh and Aged Solar Cells by the Transient Photovoltage Technique