2026-04-17T15:44:34Zhttps://recercat.cat/oai/request

oai:recercat.cat:2072/4894092026-03-31T10:57:18Zcom_2072_300912com_2072_4427col_2072_301309

Gold(I)-Catalyzed Intermolecular Reactions of Alkynes with Carbon Nucleophiles: What We Know─and What We Don't Rodrigalvarez, Jesús Arnanz, Anna Ogalla, Gala Echavarren, Antonio M. We present an overview of the scope, limitations, and challenges associated with gold(I)-catalyzed intermolecular reactions involving alkynes and alkenes, or alkynes with other alkynes, as well as mechanistically related transformations with a broader range of carbon-based nucleophiles. Emphasis is placed on reactivity patterns, selectivity issues, and the factors that currently limit the generality and synthetic applicability of these processes. 2026-03-31T09:01:08Z 2026-03-31T09:01:08Z 2026-03-31T09:01:08Z 2026-03-30 info:eu-repo/semantics/article https://hdl.handle.net/2072/489409 https://doi.org/10.1021/acscatal.6c00792 eng PID2022-136623NB-I00/MICIU/AEI/10.13039/501100011033/FEDER, UE Severo Ochoa Excellence Accreditation CEX2019-000925-S/MICIU/AEI/10.13039/501100011033 JDC2023-051192-I/MCIU/AEI/10.13039/501100011033 for Juan de la Cierva Grant (J.R.) PREP2022-000173/MCIN/AEI/10.13039/501100011033/FSE+ (to A.A.) CERCA Program/Generalitat de Catalunya http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess Attribution 4.0 International ACS Publications RECERCAT (Dipòsit de la Recerca de Catalunya)