2026-04-13T15:05:15Zhttps://recercat.cat/oai/request

oai:recercat.cat:2072/4733022024-11-04T07:13:11Zcom_2072_98col_2072_378192

00925njm 22002777a 4500 dc Cejas-Sánchez, Joel author Kajetanowicz, Anna author Grela, Karol author Caminade, Anne-Marie author Sebastián Pérez, Rosa Maria author 2023 Dendrimers, being highly branched monodispersed macromolecules, predominantly exhibit identical terminal functionalities within their structural framework. Nonetheless, there are instances where the presence of two distinct surface functionalities becomes advantageous for the fulfilment of specific properties. To achieve this objective, one approach involves implementing Janus dendrimers, consisting of two dendrimeric wedges terminated by dissimilar functionalities. The prevalent method for creating these structures involves the synthesis of dendrons that possess a core functionality that complements that of a second dendron, facilitating their coupling to generate the desired dendrimers. In this comprehensive review, various techniques employed in the fabrication of phosphorus-based Janus dendrimers are elucidated, displaying the different coupling methodologies employed between the two units. The advantages of phosphorus dendrimers over classic dendrimers will be shown, as the presence of at least one phosphorus atom in each generation allows for the easy monitoring of reactions and the confirmation of purity through a simple technique such as 31 P NMR, as these structures typically exhibit easily interpretable patterns. http://hdl.handle.net/2072/473302 Phosphorus chemistry Janus dendrimers Dendrons 31 P NMR spectroscopy Strategies for the Preparation of Phosphorus Janus Dendrimers and Their Properties