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15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes : A review Moreno-Mañas, Marcial Pleixats i Rovira, Roser Roglans, Anna Sebastián Pérez, Rosa Maria Vallribera Massó, Adelina Alkene ligands Macrocycles Heterocycles Olefin complexes Catalysis (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures. 2004 Article https://ddd.uab.cat/record/268572 urn:10.3998/ark.5550190.0005.414 urn:oai:ddd.uab.cat:268572 urn:articleid:15517012v2004n4p109 urn:oai:egreta.uab.cat:publications/b9c3cb14-4b31-4077-86c1-9e37ae3c91ff urn:scopus_id:2942607092 http://hdl.handle.net/2072/464345 eng Arkivoc ; Vol. 2004, Issue 4 (2004), p. 109-129 open access Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original. https://creativecommons.org/licenses/by/4.0/ application/pdf