2026-04-19T16:14:24Zhttps://recercat.cat/oai/request

oai:recercat.cat:2072/4643452024-11-04T04:39:21Zcom_2072_98col_2072_378192

00925njm 22002777a 4500 dc Moreno-Mañas, Marcial author Pleixats i Rovira, Roser author Roglans, Anna author Sebastián Pérez, Rosa Maria author Vallribera Massó, Adelina author 2004 (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,11-trienes, 1, are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I), and the palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures. http://hdl.handle.net/2072/464345 Alkene ligands Macrocycles Heterocycles Olefin complexes Catalysis 15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes : A review