2026-04-13T13:38:12Zhttps://recercat.cat/oai/request

oai:recercat.cat:2072/4394792026-03-13T05:51:48Zcom_2072_98col_2072_378192

00925njm 22002777a 4500 dc Hayati, Payam author Suárez García, Salvio author Gutiérrez Alonso, Ángel author Ruiz-Molina, Daniel author Morsali, Ali author Rezvani, Ali Reza author 2018 One new lead(II) coordination supramolecular complex (CSC) (1D), [Pb(L)(I)], L = CHN (1-methyl imidazole), has been synthesized under different experimental conditions. Micrometric crystals (bulk) or nano-sized materials have been obtained depending on using the branch tube method or sonochemical irradiation. All materials have been characterized by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and FT-IR spectroscopy. Single crystal X-ray analyses on complex 1 showed that Pb ion is 4-coordinated. Topological analysis shows that the complex 1 is 2,3,5C2 net. Finally, the role of reaction time and temperature on the growth and final morphology of the structures obtained by sonochemical irradiation have been studied. Coordination polymer Sonochemical process Ultrasound irradiation Morphology Sonochemical synthesis of a novel nanoscale 1D lead(II) [Pb2(L)2(I)4]n coordination Polymer, survey of temperature, reaction time parameters