2026-04-14T07:57:15Zhttps://recercat.cat/oai/request

oai:recercat.cat:2072/4288252026-03-13T04:47:07Zcom_2072_98col_2072_378192

A CaCO₃/nanocellulose-based bioinspired nacre-like material Farhadi-Khouzani, Masoud Schütz, Christina Durak, Grażyna M. Fornell Beringues, Jordina Sort Viñas, Jordi Salazar Álvarez, Germán Bergström, Lennart Gebauer, Denis Nacre continues to be an inspiration for the fabrication of strong and tough materials from renewable and earth-abundant raw materials. Herein, we showed how a nacre-like hybrid material based on nanocellulose (NC) and CaCO₃ can be prepared via the sequential infiltration of polymer-stabilised CaCO₃ liquid precursors into layers of pre-deposited NC films. Layer-by-layer assembly of the NC films followed by controlled spreading and infiltration with liquid CaCO₃ precursors generated a lamellar material with an architecture and iridescent appearance similar to those of nacre. The wettability of the NC films towards the liquid CaCO₃ precursors was controlled by hydroxyl and carboxyl functionalization of the NC fibrils and the addition of magnesium ions. The combination of a high stiffness and plasticity of the nacre-like NC/CaCO₃ hybrid materials show that excellent mechanical properties can be obtained employing a fibrillar organic constituent that is relatively hard. The fabrication of a nacre-like hybrid material via an aqueous route of assembly and infiltration processing demonstrates how a sustainable composite material with outstanding properties can be produced using the most abundant biopolymer and biomineral on earth. 2017 Article https://ddd.uab.cat/record/189211 urn:10.1039/C6TA09524K urn:oai:ddd.uab.cat:189211 urn:scopus_id:85027246298 urn:oai:egreta.uab.cat:publications/78a3568c-aa3f-449f-9f8e-7b84b313b6e0 urn:wos_id:000465911200007 urn:articleid:20507496v5n31p16128 eng Agència de Gestió d'Ajuts Universitaris i de Recerca 2014/SGR-1015 Journal of materials chemistry. A ; Vol. 5, Issue 31 (August 2017), p. 16128-16133 open access Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original. https://creativecommons.org/licenses/by/4.0/ application/pdf