2026-04-18T06:04:43Zhttps://recercat.cat/oai/requestoai:recercat.cat:2072/3556002024-12-20T15:56:42Zcom_2072_300912com_2072_4427col_2072_301309
2020-03-26T01:45:06Z
urn:hdl:2072/355600
Cyclopropane-Alkene Metathesis by Gold(I)-Catalyzed Decarbenation of Persistent Cyclopropanes
Mato, Mauro
Martín-Torres, Inmaculada
Herlé, Bart
Echavarren, Antonio M.
A gold(I)-catalyzed cyclopropane-alkene metathesis has been demonstrated with two new families of cyclopropane derivatives of naphthalene and phenanthrene (benzo-fused norcaradienes). In this process, metal carbene units are transferred from a persistent cyclopropane to an alkene, upon release of naphthalene or phenanthrene, allowing the diastereoselective synthesis of a wide range of aryl and vinyl cyclopropanes.
2019-05-15T10:31:49Z
2024-04-23T10:23:41Z
2020-03-26T01:45:06Z
2024-04-23T10:23:41Z
2019-03-27
info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
http://hdl.handle.net/2072/355600
https://doi.org/10.1039/C9OB00359B
eng
info:eu-repo/semantics/openAccess
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