2026-04-13T02:07:24Zhttps://recercat.cat/oai/request

oai:recercat.cat:2072/3059312026-01-15T14:12:31Zcom_2072_300912com_2072_4427col_2072_301309

00925njm 22002777a 4500 dc Bandeira, Nuno A. G. author Garai, Somenath author Muller, Achim author Bo, Carles author 2015 <p> The mechanism for the hydration of CO2 within a Keplerate nanocapsule is presented. A network of hydrogen bonds across the water layers in the first metal coordination sphere facilitates the proton abstraction and nucleophilic addition of water. The highly acidic properties of the polyoxometalate cluster are crucial for explaining the catalysed hydration.<br /> <br /> &nbsp;</p> http://hdl.handle.net/2072/305931 https://doi.org/10.1039/C5CC06423F The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role