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oai:recercat.cat:2072/3059312026-01-15T14:12:31Zcom_2072_300912com_2072_4427col_2072_301309

2018-01-15T16:04:00Z urn:hdl:2072/305931 The mechanism of CO2 hydration: a porous metal oxide nanocapsule catalyst can mimic the biological carbonic anhydrase role Bandeira, Nuno A. G. Garai, Somenath Muller, Achim Bo, Carles <p> The mechanism for the hydration of CO2 within a Keplerate nanocapsule is presented. A network of hydrogen bonds across the water layers in the first metal coordination sphere facilitates the proton abstraction and nucleophilic addition of water. The highly acidic properties of the polyoxometalate cluster are crucial for explaining the catalysed hydration.<br /> <br /> &nbsp;</p> 2018-01-15T16:04:00Z 2018-02-15T10:29:00Z 2024-04-23T10:35:50Z 2018-01-15T16:04:00Z 2018-02-15T10:29:00Z 2024-04-23T10:35:50Z 2015 info:eu-repo/semantics/article http://hdl.handle.net/2072/305931 https://doi.org/10.1039/C5CC06423F eng Chem. Commun. CTQ2014-52824-R SEV-2013-0319 MINECO I+D+I Severo Ochoa Excellence Accreditation 2014–2018 info:eu-repo/semantics/openAccess The Royal Society of Chemistry RECERCAT (Dipòsit de la Recerca de Catalunya)