2026-04-13T02:14:31Zhttps://recercat.cat/oai/requestoai:recercat.cat:2072/3059032026-01-15T14:12:32Zcom_2072_300912com_2072_4427col_2072_301309
RECERCAT
author
Romero, R. Martín
author
Souto, José A.
author
Muñiz , Kilian
2018-01-15T16:03:52Z2018-02-15T10:28:50Z2024-04-23T10:34:20Z
2018-01-15T16:03:52Z2018-02-15T10:28:50Z2024-04-23T10:34:20Z
2016
http://hdl.handle.net/2072/305903
https://doi.org/10.1021/acs.joc.6b01070
<p> The influence of electronic parameters on the reaction performance of hypervalent iodine(III) reagents in the vicinal diamination of styrene has been investigated. It demonstrates the influence of the relative electron density on the aryl substituent of the hypervalent iodine reagent. In these cases, compounds with donor substituents outperform the corresponding acceptor-substituted systems. In line with this observation, a rapid enantioselective diamination was observed for a preformed chiral bisimidoiodine(III) reagent. For the first time, X-ray structural data could be obtained for an isolated chiral bisimidoiodine(III).</p>
eng
2016 American Chemical Society
Substitution Effects of Hypervalent Iodine(III) Reagents in the Diamination of Styrene
info:eu-repo/semantics/article
URL
https://recercat.cat/bitstream/2072/305903/2/Muniz%252cManuscript-rev-1.pdf
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URL
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Muniz%2cManuscript-rev-1.pdf.txt