2026-04-13T03:53:04Zhttps://recercat.cat/oai/request

oai:recercat.cat:2072/3059032026-01-15T14:12:32Zcom_2072_300912com_2072_4427col_2072_301309

00925njm 22002777a 4500 dc Romero, R. Martín author Souto, José A. author Muñiz , Kilian author 2016 <p> The influence of electronic parameters on the reaction performance of hypervalent iodine(III) reagents in the vicinal diamination of styrene has been investigated. It demonstrates the influence of the relative electron density on the aryl substituent of the hypervalent iodine reagent. In these cases, compounds with donor substituents outperform the corresponding acceptor-substituted systems. In line with this observation, a rapid enantioselective diamination was observed for a preformed chiral bisimidoiodine(III) reagent. For the first time, X-ray structural data could be obtained for an isolated chiral bisimidoiodine(III).</p> http://hdl.handle.net/2072/305903 https://doi.org/10.1021/acs.joc.6b01070 Substitution Effects of Hypervalent Iodine(III) Reagents in the Diamination of Styrene