2026-04-17T02:13:26Zhttps://recercat.cat/oai/requestoai:recercat.cat:10256/265982025-03-19T18:59:13Zcom_2072_452955com_2072_2054col_2072_453073
A Superior and accessible cavitand receptor for the binding of monoterpenes and sesquiterpenes in water
Marchi Luciano, Hugo
Lopez Coll, Ricard
Álvarez Yebra, Rubén
Lledó Ponsati, Agustí
Química supramolecular
Terpens
Reconeixement molecular
Supramolecular chemistry
Terpenes
Molecular recognition
A water-soluble receptor based on resorcin[4]arene featuring 8 solubilising carboxylate units (BC4) has been obtained in a straightforward manner without chromatographic purifications. BC4 is soluble in water in a wide range of pH, and is able to accommodate guests of different sizes and shapes, including monoterpenes and sesquiterpenes, providing enhanced binding capabilities with respect to previously reported analogues. The molecular recognition events within BC4 are sensitive to subtle changes in guest shape and size, as illustrated by disparate exchange kinetics observed among the guests tested
We are grateful for financial support from grants PID2020-113181GB-I00, TED2021-130573B-I00, PID2023-146498NB-I00, and REQ2021_B_05 funded by MICIU/AEI/10.13039/501100011033 and by the European Union NextGenerationEU/PRTR. We thank AGAUR/Generalitat de Catalunya for funding (2021SGR623) and for a pre-doctoral fellowship to R. L. (2020
FI_B 00132)
Open Access funding provided thanks to the CRUE-CSIC agreement with the RSC
2025-03-19T18:59:13Z
2025-03-19T18:59:13Z
2025-03-19T18:59:13Z
2025-02-04
info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
peer-reviewed
http://hdl.handle.net/10256/26598
info:eu-repo/semantics/altIdentifier/doi/10.1039/D5QO00161G
info:eu-repo/semantics/altIdentifier/eissn/2052-4129
PID2020-113181GB-I00
TED2021-130573B-I00
PID2023-146498NB-I00
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/TED2021-130573B-I00/ES/TECNOLOGÍAS DE QUÍMICA SUPRAMOLECULAR PARA MATERIALES FOTOVOLTAICOS DE NUEVA GENERACIÓN BASADOS EN CARBONO/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-146498NB-I00/ES/ESPACIOS CONFINADOS QUIRALES PARA APLICACIONES EN CATALISIS ASIMETRICA Y MATERIALES QUIROPTICOS/
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-113181GB-I00/ES/ESPACIOS CONFINADOS FLEXIBLES PARA QUIMICA BIOINSPIRADA/
Reconeixement-NoComercial 4.0 Internacional
http://creativecommons.org/licenses/by-nc/4.0
info:eu-repo/semantics/openAccess
Royal Society of Chemistry
Organic Chemistry Frontiers, 2025, vol. undef, núm. undef, p. undef
Articles publicats (D-Q)
Marchi Luciano, Hugo Lopez Coll, Ricard Álvarez Yebra, Rubén Lledó Ponsati, Agustí 2025 A Superior and accessible cavitand receptor for the binding of monoterpenes and sesquiterpenes in water Organic Chemistry Frontiers undef undef undef