2026-04-17T13:17:13Zhttps://recercat.cat/oai/request

oai:recercat.cat:10256/203402024-06-18T12:06:43Zcom_2072_452955com_2072_2054col_2072_453062

00925njm 22002777a 4500 dc Serra Parareda, Ferran author Tarrés Farrés, Joaquim Agustí author Sanchez-Salvador, José Luis author Campano, Cristina author Pèlach Serra, Maria Àngels author Mutjé Pujol, Pere author Negro Álvarez, Carlos author Delgado Aguilar, Marc author 2021-11-01 Due to the increasing interest on lignocellulosic nanomaterials, alternative raw materials to wood sources have been explored. In this sense, annual plants can represent an important source of lignocellulose which may be used for cellulose nanofibers (CNFs) production. The present work aims at highlighting the virtues of three different non-woody resources (jute, sisal and hemp) as raw material for the production of TEMPO-mediated oxidized CNFs. The fibrillation stage was carried out by means of high-pressure homogenization (HPH), sequencing the process to obtain the initial, intermediate and final characteristics. Interestingly, it was found that while wood-based TEMPO-mediated oxidized CNFs lead highly fibrillated structures and thick gels, the obtained CNFs in this work exhibited a structure similar to cellulose nanocrystals (CNCs), particularly at high oxidation degrees, as rod-like morphologies were observed. Nonetheless, differences were observed between the selected raw materials, which was attributed to the differences on their relative recalcitrance. In addition, the rheological evaluation indicated that hemp CNFs tended to a Newtonian behavior, as flow behavior index tended to 1, leading to suspensions radically different to those obtained from wood sources. Further, the rheological behavior of the obtained nanocellulose suspensions has been found to correlate with the 2D fractal dimension of the nanostructured cellulose. Overall, the present work shows the feasibility of using non-woody plants as raw material for nanostructured cellulose production, with interesting characteristics unconceivable with wood resources The authors want to acknowledge the Spanish Ministry of Economy and Competitiveness for the funding of the project NANOPROSOST, references CTQ2017-85654-C2-1-R and CTQ2017-85654-C2-2-R. Authors want also to thank Spanish Ministry of Science and Innovation for the Juan de la Cierva aid of Cristina Campano (Ref. FJC2019-040298-I), the support of Universidad Complutense de Madrid and Banco de Santander for the grant of J.L. Sanchez-Salvador (CT17/17) and the Spanish National Centre of Electronic Microscopy for the support during image acquisition. Marc Delgado-Aguilar is a Serra Húnter Fellow Open Access funding provided thanks to the CRUE-CSIC agreement with Elsevier http://hdl.handle.net/10256/20340 Materials nanoestructurats Nanostructured materials Fibres de cel·lulosa Cellulose fibers Tuning morphology and structure of non-woody nanocellulose: ranging between nanofibers and nanocrystals