2026-04-13T01:42:58Zhttps://recercat.cat/oai/requestoai:recercat.cat:10256/194992024-06-18T13:56:15Zcom_2072_452955com_2072_2054col_2072_453073
RECERCAT
author
Ampßler, Torsten
author
Monsch, Georg
author
Popp, Jens
author
Riggenmann, Tobias
author
Salvador Sedano, Pedro
author
Schröder, Daniel
author
Klüfers, Peter
2024-06-18T13:56:15Z
2024-06-18T13:56:15Z
2020-07-20
http://hdl.handle.net/10256/19499
Aquest mateix article està publicat a l'edició alemanya d''Angewandte Chemie' (ISSN 0044-8249, EISSN 1521-3757), 2002, vol.132, núm. 30, p. 12480-12485. DOI https://doi.org/10.1002/ange.202003122Nitrosyl–metal bonding relies on the two interactions between the pair of N–O‐π* and two of the metal's d orbitals. These (back)bonds are largely covalent, which makes their allocation in the course of an oxidation‐state determination ambiguous. However, apart from M‐N‐O‐angle or net‐charge considerations, IUPAC′s “ionic approximation” is a useful tool to reliably classify nitrosyl metal complexes in an orbital‐centered approachDeutsche Forschungsgemeinschaft. Grant Number: KL 624/18-1
Ministerio de Ciencia, Innovación y Universidades. Grant Number: PGC2018-098212-B-C22
Attribution 4.0 International http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess
Enllaços químics
Chemical bonds
Orbitals moleculars
Molecular orbitals
Química quàntica
Quantum chemistry
Not Guilty on Every Count: The “Non‐Innocent” Nitrosyl Ligand in the Framework of IUPAC′s Oxidation‐State Formalism
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion peer-reviewed