Title:
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Relationship between the two-component system 1-Br-adamantane + 1-Cl-adamantane and the high-pressure properties of the pure components
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Author:
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Barrio Casado, María del; Levit Valenzuela, Rafael; Lloveras Muntané, Pol Marcel; Aznar Luque, Araceli; Negrier, Philippe; Mondieig, Denise; Tamarit Mur, José Luis
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Other authors:
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Universitat Politècnica de Catalunya. Departament de Física; Universitat Politècnica de Catalunya. GCM - Grup de Caracterització de Materials; Universitat Politècnica de Catalunya. CEMAD - Caracterització Elèctrica de Materials i Dispositius |
Abstract:
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The temperature-composition phase diagram of the two-component system 1-Br-adamantane and 1-Cl-adamantane has been determined by means of thermal analysis techniques and X-ray powder diffraction from the low-temperature phase to the liquid state.
The crossed isopolymorphism formalism has been applied to the two-component system to infer the normal pressure properties of the orthorhombic metastable phase of 1-Cl-adamantane at normal pressure. The experimental pressure-temperature phase diagrams for the involved compounds are related to the two-phase equilibria determined at normal pressure and inferences about the monotropic behavior of the aforementioned orthorhombic phase are discussed. |
Abstract:
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Peer Reviewed |
Subject(s):
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-Àrees temàtiques de la UPC::Física -High pressure (Technology) -High pressure -Polymorphism -Two-component system -Polimorfisme -Pressió |
Rights:
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Document type:
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Article - Submitted version Article |
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