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Títol:
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Cooperative effects between arginine and glutamic acid in the amino acid catalyzed aldol reaction
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Autor/a:
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Valero González, Guillem; Moyano i Baldoire, Albert
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Altres autors:
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Universitat de Barcelona |
Abstract:
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Catalysis of the aldol reaction between cyclohexanone and 4-nitrobenzaldehyde by mixtures of L-Arg and of L-Glu in wet DMSO takes place with higher enantioselectivity (up to a seven-fold enhancement in the anti- aldol for the 1:1 mixture) than that observed when either L-Glu or L-Arg alone are used as the catalysts. These results can be explained by the formation of a catalytically active hydrogen-bonded complex between both amino acids, and demonstrate the possibility of positive cooperative effects in catalysis by two different α-amino acids. Chirality |
Matèries:
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-Aminoàcids -Catàlisi -Química supramolecular -Àcid glutàmic -Quiralitat -Amino acids -Catalysis -Supramolecular chemistry -Glutamic acid -Chirality |
Drets:
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(c) Wiley, 2016
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Tipus de document:
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Article Article - Versió acceptada |
Publicat per:
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Wiley
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