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Reverse osmosis membrane composition, structure and performance modification by bisulphite, iron(III), bromide and chlorite exposure
Ferrer, Olga; Gibert Agulló, Oriol; Cortina Pallás, José Luís
Universitat Politècnica de Catalunya. Departament d'Enginyeria Química; Universitat Politècnica de Catalunya. SETRI - Grup de Tècniques de Separació i Tractament de Residus Industrials
Reverse osmosis (RO) membrane exposure to bisulphite, chlorite, bromide and iron(III) was assessed in terms of membrane composition, structure and performance. Membrane composition was determined by Rutherford backscattering spectrometry (RBS) and membrane performance was assessed by water and chloride permeation, using a modified version of the solution-diffusion model. Iron(III) dosage in presence of bisulphite led to an autooxidation of the latter, probably generating free radicals which damaged the membrane. It comprised a significant raise in chloride passage (chloride permeation coefficient increased 5.3–5.1 fold compared to the virgin membrane under the conditions studied) rapidly. No major differences in terms of water permeability and membrane composition were observed. Nevertheless, an increase in the size of the network pores, and a raise in the fraction of aggregate pores of the polyamide (PA) layer were identified, but no amide bond cleavage was observed. These structural changes were therefore, in accordance with the transport properties observed.
Peer Reviewed
Àrees temàtiques de la UPC::Enginyeria química
Reverse osmosis
Chemical process control
Reverse osmosis
Degradation
Bisulphite
Iron
Bromide
Rutherford backscattering spectrometry
Osmosi inversa
Processos químics
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
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