Title:
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Relaxation dynamics of Fe55Cr10Mo14C15B6 metallic glass explored by mechanical spectroscopy and calorimetry measurements
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Author:
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Liu, Chaoren; Madinehei, Seyed Milad; Pineda Soler, Eloi; Crespo Artiaga, Daniel
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Other authors:
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Universitat Politècnica de Catalunya. Departament de Física; Universitat Politècnica de Catalunya. GCM - Grup de Caracterització de Materials |
Abstract:
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In this work, the mechanical relaxation dynamics of Fe55Cr10Mo14C15B6 metallic glass is explored by mechanical spectroscopy. The temperature-dependent loss modulus E″(T) shows the features of β relaxation well below glass transition temperature Tg. This β relaxation can be well described in the framework of anelastic theory by a thermal activated process with activation energy of 165 kJ mol−1. Structural relaxation, also known as physical aging, has a large effect on the glass properties. The activation energy spectrum of structural relaxation is characterized by differential scanning calorimetry measuring the heat flow difference between as-quenched and relaxed states. The obtained energy spectrum is well described by a lognormal distribution with maximum probability activation energy of 176 kJ mol−1. The obtained activation energy of structural relaxation is similar to that of β relaxation observed from mechanical spectroscopy. Both values are also close to the Johari–Goldstein β relaxation estimated by the empirical rule Eβ = 26RTg. |
Abstract:
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Peer Reviewed |
Subject(s):
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-Àrees temàtiques de la UPC::Enginyeria dels materials -Metallic glasses -Metallic glasses -- Viscosity -Anelastic -Mechanical relaxation -Metallic glass -Physical aging -Structural relaxation -Viscosity -Vidres metàl·lics |
Rights:
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http://creativecommons.org/licenses/by-nc-nd/3.0/es/ |
Document type:
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Article - Submitted version Article |
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