Poly(butylene 2,5-furan dicarboxylate-co-butylene succinate) via ring opening polymerization

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dc.contributor	Universitat Politècnica de Catalunya. Departament d'Enginyeria Química
dc.contributor	Universitat Politècnica de Catalunya. POL - Polímers Industrials Avançats i Biopolímers Tecnològics
dc.contributor.author	Morales Huerta, Juan Carlos
dc.contributor.author	Ciulik, Claudio
dc.contributor.author	Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon
dc.contributor.author	Muñoz Guerra, Sebastián
dc.date	2016
dc.identifier.citation	Morales, J., Ciulik, C., Martinez de Ilarduya, A., Muñoz, S. Poly(butylene 2,5-furan dicarboxylate-co-butylene succinate) via ring opening polymerization. A: Reunión del Grupo Especializado de Polímeros (GEP) de la RSEQ y RSEF. "Avances en materiales poliméricos: XIV Reunión del grupo especializado de polímeros (GEP) de la RSEQ y RSEF [5-8 de septiembre]: libro de resúmenes GEP2016". Burgos: 2016, p. 52-54.
dc.identifier.citation	978-84-16283-26-2
dc.identifier.uri	http://hdl.handle.net/2117/91095
dc.language.iso	eng
dc.relation	http://wwww.ubu.es/servicio-de-publicaciones-e-imagen-institucional
dc.relation	info:eu-repo/grantAgreement/ES/1PE/MAT2012-38044-C03-03
dc.rights	info:eu-repo/semantics/openAccess
dc.rights	http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subject	Àrees temàtiques de la UPC::Enginyeria química
dc.subject	Ring-opening polymerization
dc.subject	Copolymers
dc.subject	Polyesters
dc.subject	Ring opening polymerization
dc.subject	PBF and PBS cyclic oligomers
dc.subject	copolyesters
dc.subject	sustainable polyesters
dc.subject	sugar based polyesters
dc.subject	thermal properties
dc.subject	random copolyesters
dc.subject	Polièsters
dc.subject	Copolímers
dc.subject	Polimerització
dc.title	Poly(butylene 2,5-furan dicarboxylate-co-butylene succinate) via ring opening polymerization
dc.type	info:eu-repo/semantics/publishedVersion
dc.type	info:eu-repo/semantics/conferenceObject
dc.description.abstract	In this communication we wish to report on the synthesis of PBFxSy copolyesters by ring opening polymerization (ROP) using either organometallic catalysts or enzymes. The ROP of macrocyclic oligomers (MCOs) has been demonstrated to offer significant advantages over the traditional polycondensation method. The synthesis of MCOs of butylene succinate c(BS)n is known from long whereas MCOs of butylene 2,5-furandicarboxylate (c(BF)n) have not been reported until very recently. In this work, the synthesis of c(BF)n and c(BS)n has been performed using high dilution condensation (HDC) and enzymatic cyclization, respectively. Mixtures of dimer to tetramer and dimer to nonamer were obtained for c(BF)n and c(BS)n respectively.

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