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Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands
Orgué Gassol, Sílvia; Flores-Gaspar, Areli; Biosca, Maria; Pàmies, Oscar; Diéguez, Montserrat; Riera i Escalé, Antoni; Verdaguer i Espaulella, Xavier
Universitat de Barcelona
The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.
Hidròlisi
Lligands
Catàlisi asimètrica
Compostos de bor
Hydrolysis
Ligands
Enantioselective catalysis
Boron compounds
cc by (c) Orgué Gassol, Sílvia et al., 2015
http://creativecommons.org/licenses/by/4.0
Article
info:eu-repo/semantics/publishedVersion
Royal Society of Chemistry
         

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