Título:
|
Versatile methodology to hydrate alkynes, in the presence of a wide variety of functional groups, with Mercury(II) p-Toluensulfonamidate, under catalytic, mild and neutral conditions
|
Autor/a:
|
Corominas, Albert (Corominas Tarruella); Montaña Pedrero, Ángel-Manuel
|
Otros autores:
|
Universitat de Barcelona |
Abstract:
|
A method to generate carbonylic compounds from alkynes under mild and neutral conditions, with excellent functional group compatibility and high yields, is described. Hydration takes place under catalytic conditions by using from 0.1 to 0.2 equivalents of the easily available and inexpensive mercury(II) p-toluensulfonamidate in a hydroalcoholic solution. After use the catalyst is iner tized and/or recycled ... |
Materia(s):
|
-Compostos carbonílics -Química orgànica -Carbonyl compounds -Organic chemistry |
Derechos:
|
(c) Taylor and Francis, 2013
|
Tipo de documento:
|
Artículo Artículo - Versión aceptada |
Editor:
|
Taylor and Francis
|
Compartir:
|
|