Total synthesis of (-)-isoavenaciolide

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RECERCAT Home > Universitat de Barcelona > Química Inorgànica i Orgànica > Articles publicats en revistes (Química Inorgànica i Orgànica) > View document

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Title:	Total synthesis of (-)-isoavenaciolide
Author:	Santos, David; Ariza Piquer, Xavier; García Gómez, Jordi; Lloyd-Williams, Paul; Martínez Laporta, Agustín; Sánchez Zarzalejo, Carolina
Other authors:	Universitat de Barcelona
Abstract:	An enantioselective approach to (-)-isoavenaciolide was achieved starting from 1- undecyn-3-ol. The synthesis relied upon the preparation of a chiral 4-silyloxy-2-alkenylborane by hydroboration of a protected 2,3-allenol and subsequent stereoselective addition to 2- thiophenecarboxaldehyde
Subject(s):	-Biomolècules -Productes naturals -Síntesi asimètrica -Medicaments antibacterians -Fungicides -Biomolecules -Natural products -Asymmetric synthesis -Antibacterial agents -Fungicides
Rights:	(c) American Chemical Society , 2013
Document type:	Article Article - Accepted version
Published by:	American Chemical Society
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