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Synthesis of (E)-4-bromo-3-methoxybut-3-en-2-one, the key fragment in the polyhydroxylated chain common to oscillariolide and phormidolides A-C
Gil, Alejandro; Lamariano Merketegi, Janire; Lorente Crivillé, Adriana; Albericio Palomera, Fernando; Álvarez Domingo, Mercedes
Universitat de Barcelona
The terminal bromomethoxydiene (BMD) moiety of the polyhydroxylated chain present in phormidolides and oscillariolides has been synthesized for first time. Several strategies for the stereoselective synthesis of the 4-bromo-3-methoxybut-3-en-2-ones are described. Furthermore, a preliminary study to successfully introduce this fragment within the polyol chain and introduction of the fatty acid allowed corroborate the end structure of the polyol.
Productes naturals
Síntesi asimètrica
Química orgànica
Natural products
Asymmetric synthesis
Organic chemistry
(c) Wiley-VCH, 2016
info:eu-repo/semantics/embargoedAccess
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info:eu-repo/semantics/acceptedVersion
Wiley-VCH
         

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