Highly efficient, multigram and enantiopure synthesis of (S)-2-(2,4′-bithiazol-2-yl)pyrrolidine

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RECERCAT Home > Universitat de Barcelona > Farmacologia, Toxicologia i Química Terapèutica > Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) > View document

To access the full text documents, please follow this link: http://hdl.handle.net/2445/54982

dc.contributor	Universitat de Barcelona
dc.contributor.author	Just Baringo, Xavier
dc.contributor.author	Bruno, Paolo
dc.contributor.author	Albericio Palomera, Fernando
dc.contributor.author	Álvarez Domingo, Mercedes
dc.date	2014-06-13T10:51:08Z
dc.date	2014-06-13T10:51:08Z
dc.date	2011-08-16
dc.date	2014-06-13T10:51:08Z
dc.identifier.citation	0040-4039
dc.identifier.citation	598512
dc.identifier.uri	http://hdl.handle.net/2445/54982
dc.format	3 p.
dc.format	application/pdf
dc.language.iso	eng
dc.publisher	Elsevier Ltd
dc.relation	Versió postprint del document publicat a: http://dx.doi.org/10.1016/j.tetlet.2011.07.128
dc.relation	Tetrahedron Letters, 2011, vol. 52, num. 42, p. 5435-5437
dc.relation	http://dx.doi.org/10.1016/j.tetlet.2011.07.128
dc.rights	(c) Elsevier Ltd, 2011
dc.rights	info:eu-repo/semantics/openAccess
dc.subject	Productes naturals
dc.subject	Antibiòtics
dc.subject	Síntesi de pèptids
dc.subject	Compostos heterocíclics
dc.subject	Enantiòmers
dc.subject	Natural products
dc.subject	Antibiotics
dc.subject	Peptide synthesis
dc.subject	Heterocyclic compounds
dc.subject	Enantiomers
dc.title	Highly efficient, multigram and enantiopure synthesis of (S)-2-(2,4′-bithiazol-2-yl)pyrrolidine
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.description.abstract	(S)-2-(4-Bromo-2,4"-bithiazole)-1-(tert-butoxycarbonyl)pyrrolidine ((S)-1) was obtained as a single enantiomer and in high yield by means of a two-step modified Hantzsch thiazole synthesis reaction when bromoketone 3 and thioamide (S)-4 were used. Further conversion of (S)-1 into trimethyltin derivative (S)-2 broadens the scope for further cross-coupling reactions.

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