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Highly efficient, multigram and enantiopure synthesis of (S)-2-(2,4′-bithiazol-2-yl)pyrrolidine
Just Baringo, Xavier; Bruno, Paolo; Albericio Palomera, Fernando; Álvarez Domingo, Mercedes
Universitat de Barcelona
(S)-2-(4-Bromo-2,4"-bithiazole)-1-(tert-butoxycarbonyl)pyrrolidine ((S)-1) was obtained as a single enantiomer and in high yield by means of a two-step modified Hantzsch thiazole synthesis reaction when bromoketone 3 and thioamide (S)-4 were used. Further conversion of (S)-1 into trimethyltin derivative (S)-2 broadens the scope for further cross-coupling reactions.
Productes naturals
Antibiòtics
Síntesi de pèptids
Compostos heterocíclics
Enantiòmers
Natural products
Antibiotics
Peptide synthesis
Heterocyclic compounds
Enantiomers
(c) Elsevier Ltd, 2011
Artículo
info:eu-repo/semantics/acceptedVersion
Elsevier Ltd
         

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