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| dc.contributor | Universitat de Barcelona |
|---|---|
| dc.contributor.author | Isidro Llobet, Albert |
| dc.contributor.author | Just Baringo, Xavier |
| dc.contributor.author | Ewenson, Ariel |
| dc.contributor.author | Álvarez Domingo, Mercedes |
| dc.contributor.author | Albericio Palomera, Fernando |
| dc.date | 2007 |
| dc.identifier.citation | 0006-3525 |
| dc.identifier.uri | http://hdl.handle.net/2445/48634 |
| dc.description.abstract | A double side-reaction, consisting in the formation of Fmoc--Ala-OH and Fmoc--Ala-AA-OH, during the preparation of Fmoc protected amino acids (Fmoc-AA-OH) with Fmoc-OSu is discussed. Furthermore, the new Fmoc-2-MBT reagent is proposed for avoiding these side-reactions as well as the formation of the Fmoc-dipeptides (Fmoc-AA-AA-OH) and even tripeptides, which is another important side-reaction when chloroformates such as Fmoc-Cl is used for the protection of the -amino function of the amino acids. |
| dc.format | 5 p. |
| dc.format | application/pdf |
| dc.language.iso | eng |
| dc.publisher | Wiley |
| dc.relation | Biopolymers, 2007, vol. 88, num. 5, p. 733-737 |
| dc.rights | (c) Wiley, 2007 |
| dc.rights | info:eu-repo/semantics/openAccess |
| dc.subject | Reaccions químiques |
| dc.subject | Síntesi de pèptids |
| dc.subject | Chemical reactions |
| dc.subject | Peptide synthesis |
| dc.title | Fmoc-2-Mercaptobenzothiazole (MBT), for the Introduction of the Fmoc Moiety Free of Side-Reactions |
| dc.type | info:eu-repo/semantics/article |
| dc.type | info:eu-repo/semantics/submittedVersion |
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