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Network structure and thermomechanical properties of hybrid DGEBA networks cured with 1-methylimidazole and hyperbranched poly(ethyleneimine)s
Fernández Francos, Xavier; Santiago, David; Ferrando Piera, Francesc; Ramis Juan, Xavier; Salla Tarragó, José María; Serra Albet, Àngels; Sangermano, Marco
Universitat Politècnica de Catalunya. Departament de Màquines i Motors Tèrmics; Universitat Politècnica de Catalunya. TERFIQ - Grup de Termodinàmica i Fisico-Química
he use of commercially available hyperbranched poly(ethyleneimine)s (Lupasol TM , BASF) as polymeric modifiers in diglycidyl ether of bisphenol A thermosetting formulations using 1-methylimidazole (MI) as anionic initiator has been studied. Poly(ethyleneimine)s can get incorporated into the network structure by condensation of amine and epoxy groups. The excess, over-stoichiometric epoxy groups can undergo ani- onic homopolymerization initiated by MI. The thermal, dyna- momechanical, and mechanical properties of the resulting materials have been determined using DSC, thermomechanical analysis (TMA), dynamomechanical analysis (DMA), and me- chanical testing. The effect of the different amine modifiers on the MI networks, determined by their structure, is complex. Low initiator content and high molecular weight modifiers cre- ate significant mobility restrictions, which have a strong effect on the glass transition temperature and the apparent crosslink- ing density of the cured materials.
Àrees temàtiques de la UPC::Enginyeria dels materials::Materials plàstics i polímers
Àrees temàtiques de la UPC::Enginyeria mecànica
Polymers
Thermosetting composites
epoxy thermosets
hyperbranched
impact strength
mechanical properties
network structure
thermal properties
thermomechanical properties
thermosets
Polímers
Termoplàstics
Attribution-NonCommercial-NoDerivs 3.0 Spain
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
info:eu-repo/semantics/publishedVersion
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