An enantioselective synthetic route to cis-2,4-disubstituted and 2,4-bridged piperidines

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Title:	An enantioselective synthetic route to cis-2,4-disubstituted and 2,4-bridged piperidines
Author:	Amat Tusón, Mercedes; Pérez Bosch, Maria; Minaglia, Annamaria T.; Bosch Cartes, Joan
Other authors:	Universitat de Barcelona
Abstract:	A synthetic route to enantiopure cis-2,4-disubstituted and 2,4-bridged piperidines is reported, the key step being a stereoselective conjugate addition of an organocuprate to a phenylglycinol-derived unsaturated lactam bearing a substituent at the 8a-position.
Subject(s):	-Compostos organometàl·lics -Coure -Síntesi orgànica -Lactames -Organometallic compounds -Copper -Synthetic organic chemistry -Lactams
Rights:	(c) American Chemical Society , 2008
Document type:	Article Article - Accepted version
Published by:	American Chemical Society
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