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Phase-field modelling of microstructural evolution in primary crystallization
Bruna Escuer, Pere; Pineda Soler, Eloi; Crespo Artiaga, Daniel
Universitat Politècnica de Catalunya. Departament de Física Aplicada; Universitat Politècnica de Catalunya. GCM - Grup de Caracterització de Materials
One of the main routes to obtain nanostructured materials is through the primary crystallization of metallic glasses. In such transformations, crystallites with a different composition than the amorphous precursor grow with a diffusion-controlled regime. Particle growth is slowed and eventually halted by the impingement between the concentration gradients of surrounding particles. Primary crystallization kinetics is not well described by the KJMA equation, and this fact was generally ascribed to both the soft-impingement effect and the non-random nucleation. However, recent phase-field simulations showed that the underlying physical reason is the change in the local diffusion properties of the amorphous precursor due to the variation of the composition during the transformation. The kinetics of primary crystallization is thus well described by considering a diffusion coefficient of the slowest diffusing species dependent on the local concentration. The nanostructure developed in such transformations is a key point to explain the macroscopic properties of these materials. In this work the grain size distributions obtained in realistic phase-field simulations of transformations with continuous nucleation and both constant and variable diffusion coefficient are presented. The obtained distributions are analyzed and the physical mechanisms responsible of their different features are recognized.
Àrees temàtiques de la UPC::Enginyeria dels materials
Metallic glasses
Nucleation and growth transformations
Crystallization kinetics
Microstructure development
Diffusion controlled growth
Phase-field modelling
Vidres metàl·lics
Attribution-NonCommercial-NoDerivs 2.5 Spain

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