Morphology and thermomechanical properties of melt-mixed polyoxymethylene/polyhedral oligomeric silsesquioxane nanocomposites

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dc.contributor	Universitat Politècnica de Catalunya. Departament de Ciència dels Materials i Enginyeria Metal·lúrgica
dc.contributor	Universitat Politècnica de Catalunya. POLYCOM - Polimers i compòsits: tecnologia
dc.contributor.author	Sánchez Soto, Miguel
dc.contributor.author	Illescas Fernandez, Silvia
dc.contributor.author	Milliman, Henry
dc.contributor.author	Schiraldi, David A.
dc.contributor.author	Arostegui, Asier
dc.date	2010
dc.identifier.citation	Sánchez, M. [et al.]. Morphology and thermomechanical properties of melt-mixed polyoxymethylene/polyhedral oligomeric silsesquioxane nanocomposites. "Macromolecular materials and engineering", 2010, vol. 295, p. 846-858.
dc.identifier.citation	1438-7492
dc.identifier.citation	10.1002/mame.201000064
dc.identifier.uri	http://hdl.handle.net/2117/12601
dc.language.iso	eng
dc.rights	info:eu-repo/semantics/openAccess
dc.subject	Àrees temàtiques de la UPC::Enginyeria dels materials::Materials plàstics i polímers
dc.subject	Nanocomposites (Materials)
dc.subject	Nanocompòsits (Materials)
dc.title	Morphology and thermomechanical properties of melt-mixed polyoxymethylene/polyhedral oligomeric silsesquioxane nanocomposites
dc.type	info:eu-repo/semantics/publishedVersion
dc.type	info:eu-repo/semantics/article
dc.description.abstract	The influence of the functionalization of fully condensed POSS cages on the properties of POMbased nanocomposites is studied. POSS with different organic substituents [glycidylethyl, aminopropylisobutyl, and poly(ethylene glycol)] are taken into account and melt mixed with POM. Good dispersion was achieved upon the addition of amino functionalized POSS, leading to an increase on the thermal decomposition temperature under nitrogen atmosphere up to 50 8C. However, mm-size aggregates were observed for other nanocomposites. There is no significant change in other thermal properties of the nanocomposites. The relationships among these effects and the morphological characteristics of the systems were analyzed.

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