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Title:
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Voltammetric lability of multiligand complexes: the case of ML2
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Author:
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Puy Llorens, Jaume; Cecilia Averós, Joan; Galceran i Nogués, Josep; Town, Raewyn M.; Leeuwen, Herman P. van
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Notes:
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The voltammetric lability of a complex system, where a metal ion M and a ligand L form the species ML and ML2, is examined. Together with the rigorous numerical simulation of the problem, two limiting cases are analysed for the overall process ML2 → M: (i) the most common case for aqueous complexes, where ML → M is the kinetically limiting step and (ii) the case where ML2 → ML is limiting. In both cases, analytical expressions for the lability criteria are provided which show good agreement with the results obtained from the rigorous numerical simulation of the problem. |
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Subject(s):
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-Voltametria
-Metalls
-Voltammetry
-Metals |
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Rights:
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(c) Elsevier, 2004
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Document type:
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Article
Article - Accepted version |
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Published by:
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Elsevier
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Share:
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